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According to experts, the power-generating complex in the entire chain from fuel production to the thermal energy application efficiency of the use of energy resources is only 44 %. That necessitates the researching of ways to enhance efficiency of organic fuel burning. One of the way to solve the problem is the burning fuel in the swirl burner with using of ionizated air. Domestic and international researches have shown that atomic oxygen increases the completeness combustion and reduces the number emitted into the atmosphere of pollutant emissions. At present, the reduction of air pollution of toxic substances allocated by industrial enterprises, is one of the most important problems facing humanity. Air pollution has a unhealthy exposure for humans and the environment. In this paper estimated effectiveness of existing chemical kinetic mechanisms of natural gas burning for the swirl burner and mechanisms unhealthy emissions produced based on the results of the evaluation. The purpose of work is to increase the effectiveness of fuel combustion and technical and economic, as well as environmental indicators in the swirl burner on the heat-and-power plant.