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The paper provides an overview of the geological structure and presents new data on petrography and geochemistry of igneous rocks of the Tekturmas accretionary complex (TAC). Consideration is being given to the age, petrogenesis and probable tectonic settings of formation of igneous rocks. It is shown that the TAC and adjacent ophiolite belt are parts of the Late Cambrian -Ordovician Pacific-type orogenic belt formed at an active margin of the Paleo-Asian Ocean. The TAC is dominated mainly by tholeiitic mafic igneous rocks (basalt, dolerite, gabbro). There are recognized three groups of rocks: high-Ti, medium-Ti and low-Ti. Geological and geochemical features of TAC igneous rocks suggest their formation in three tectonic settings: mid-ocean ridge (medium-Ti), oceanic island/seamount (high-Ti) and over subduction zones (low-Ti).

The Chadobets alkaline ultramafic carbonatite complex is located on the Siberian craton within the southern boundary of the Permian-Triassic plume activity. The dating of xenogenic zircons from the weathering crust of carbonatites of the Chuktukon complex yielded four clusters with ages of 1870-1820, 495-385, 290-210 and 215-162 Ma. The first two clusters correspond to the dates of activity of Paleoproterozoic granitoid magmatism and Paleozoic alkaline-mafic tectono-magmatic activity, widely occurred in the Siberian craton and its southern framing. The age of crystallization of alkaline rocks of the Chadobets complex falls within the interval of 255-240 Ma. Ar-Ar dating of damtjernite and carbonatite minerals of the Chuktukon complex falls within the intervals of 250.5±3.7 and 247.1±5.7 Ma, respectively. The crystallization ages of the mela-aillikites and damtjernites of the Terina complex, according to the Ar-Ar dating, correspond to the intervals of 257.4±3.9, 241.1±3.7, and 240±3.6 Ma. The age interval of 215-162 Ma based on zircons from the carbonatite weathering crust of the Chuktukon complex reflects the geochronology of superimposed processes and indicates the different stages of alteration of igneous rocks of the Chadobets complex. The data obtained on the age of crystallization of alkaline rocks of the Chadobets complex are consistent with the age interval of Siberian plume activity within a large igneous province (LIP).