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The equilibrium phase diagrams of NaCl−ZnCl 2 − H 2 O system at 260.35 and 250.15 K were studied by method of isothermal solution saturation, wet residues, and thermogravimetric analysis. Water content in precipitate at these temperatures for hydrate 2NaCl•ZnCl 2 •nH 2 O was determined, n = 3. Densities of ternary NaCl−ZnCl 2 −H 2 O solutions were measured at 288.15−321.35 K and compared with values predicting by the Laliberte model. It was shown that the model provides mainly underestimated density values.

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