A method is developed for calculating the three parameters needed to characterize the carbon number distribution of products of the Fischer-Tropsch synthesis. Experimental data are fit by a modified Schulz-Flory model that has two chain growth probabilities, using nonlinear regression. Excellent fit is shown for data from precipitated iron and fused magnetite catalysts. The model is used to calculate selectivity information of interest in catalyst comparison and reactor design. Advantages of this method over asymptotic regression methods are discussed in detail.
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