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The paper covers aspects of the technology of fibre electrospinning for the production of nonwoven fabrics for various application areas. The conditions of forming nano- and microfibres from solutions of collagen hydrolyzate and dibutyrylchitine were studied as well as polymer-polymer complexes based on polyacrylic acid, polyvinyl alcohol and polyethylene oxide. A comparative analysis of different methods of electrospinning – electrocapillary, electric and NanospiderTM , was conducted. Promising application areas of non-woven fabrics in medicine sanitation as well as for clothing and footwear production are shown.