A new synthesis of polyvinyl chloride (PVC-grafted-4-amicacid phenol, which consist of a reaction between poly (vinyl chloride ) and 4-amic acid phenol . Grafting structure has been checked by, FTIR, 1HNMR, 13C NMR, TG, DSC and X-RAY .The grafting of PVC work to changes the surface properties such as catalytic ability, adhesion and adsorption capacity. This paper describes grafting of polyvinyl chloride (PVC) as adsorbent for pb+2 ions removal. The adsorption process recorded comparatively rapid uptake of pb+2 by the new PVC-grafted-4-amicacid phenol which was mainly complexation controlled.