This work presents the results of tribological and structural investigations of polymer composites based on polytetrafluoroethylene and muscovite. It is shown that the wear resistance of the composites increased up to 675 times in comparison with the initial polymer. The increase of wear resistance is attributed to the occurrence of tribo-oxidation processes on the friction surface, which have been confirmed by various investigations. Thus, IR spectroscopy showed that carboxylate anions are formed on the friction surface of composites during friction processes. An increase in oxygen and a decrease in carbon and fluorine concentrations on the composite surface have been detected after friction using the EDS analysis. The results of XPS have confirmed the destruction of C-F bonds and the formation of new oxygen-containing compounds. These research methods indicated the occurrence of tribo-oxidative processes during friction.
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