A proper charge in an electric vehicle (EV) battery allows it to have a longer useful life and lower maintenance costs. For this purpose, the voltage and current supplied to the battery must be precisely regulated. In this article, the model of a phase-shifted full-bridge (PSFB) converter is obtained. Moreover, a dual control loop was designed to regulate the state of charge of a lithium ferrofosfate (LiFePO4) battery. The autoregressive exogenous (ARX) model is used to model the system. Once the plant model is obtained, it is controlled using a classical controller. A couple of cases are evaluated where the control parameters are modified, and the best approach is selected. From the obtained model, the controller is designed for the proposed cases. The theoretical controller response is compared with the experimental response. The results show a 94% accuracy of the model. In the same way, the result obtained from the controller is accurate in a 96% by comparing it with a simulation. Both the modeling and the control obtained experimentally resemble the results obtained theoretically. The controller manages to respond as expected in all proposed cases.