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Far-Uv Spectra of H and OH 1029 given amount of adsorbed alcohols on the mercury electrode. In more nearly perpendicular orientation, the projected area of normal aliphatic alcohols on the mercury electrode is about the same. Thus, the inhibition effect in this orientation is proportional to the amount of adsorbed alcohols on the mercury and not on the alcohol itself. The deviation of the inhibition effect from regularity in the medium concentration range is explained by some perpendicular orientation and some parallel. With increasing alcohol concentration, it is reasonable that perpendicular orientation predominates; therefore, the rate constants in the presence of the different alcohols become super-imposable on each other at a given relative concentration of the alcohol.

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