The base-catalyzed hydroarsination reactions of
(H3CC⋮CPPh2)Mo(CO)5
and [H2CCCH(DBP)]Mo(CO)5
(DBP
= dibenzophosphole) give several different products as a function of
reaction conditions. These products have
been characterized by elemental analyses, physical properties,
1H, 13C{1H}, and
31P{1H} NMR spectroscopy,
and, in two cases, X-ray crystallography.
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