An experimental set-up and specific sample containment allowing high-temperature in situ EXAFS measurements of radioactive, air-sensitive and corrosive fluoride salts is described. First results are reported and compared with molecular dynamics simulations of the highly disordered liquid salts.
The short-range structures of LiF-ThF4, NaF-AnF4, KF-AnF4, and Cs-AnF4 (An = Th, U), were probed using in situ high temperature Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy. Signally, the EXAFS...
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