As a result of analysis based on the observed data for BOD, COD and TOC in order to manage non-biodegradable organics in the Geumho River, COD/BOD ratio was analyzed as the occupying predominance proportion. In this study, the classification(changes in water quality measurement : increase, equal, decrease) and measurement of BOD and COD were analyzed for trends over the past 10 years from 2005 to 2014 in the Geumho River. The Geumho River is expected to need non-biodegradable organics management because BOD was found to be reduced 61.1% and COD was found to be increased 50%. As a result of the analysis of land use, the Geumho-A is a unit watershed area of 921.13 km 2 , which is the most common area that is occupied by forests. The Geumho-B is a unit watershed area of 436.8 km 2 , which is the area that is highest occupied by agriculture and grass of 24.84%. The Geumho-C is a unit watershed area of 704.56 km 2 accounted for 40.29% of the entire watershed, which is the area that is occupied by urban of 15.12%. Load of non-biodegradable organics, which is not easy biodegradable according to the discharge, appeared to be increased because flow coefficient of COD and TOC at the Geumho-B were estimated larger than 1 value. The management of non-point sources of agricultural land is required because the Geumho-B watershed area occupied by the high proportion of agriculture and field. In this segment it showed to increase the organics that biodegradation is difficult because the ratio of BOD and TOC was decreased rapidly from GR7 to GR8. Thus, countermeasures will be required for this.

Milyanggang mid-watershed is located in downstream of Nakdong river basin. The pollutants from that watershed have an direct effect on Nakdong river water quality and it's control is important to manage a water quality of Nakdong river. A target year of Milyanggang mid-watershed water environment management plan is 2013. To predict a water quality at downstream of Milyang river, we have investigated and forecasted the pollutant source and it's loading. There are some plan to construction the sewage treatment plants to improve the water quality of Milyang river. Those are considered on predicting water quality. As results, it is shown that the population of Milyanggang mid-watershed is 131,857 and sewerage supply rate is 62.2% and the livestock is 1,775.300 in 2006. It is estimated that the population is 123,921, the sewerage supply rate is 75.5% in 2013. The generated loading of BOD and TP is 40,735 kg/day and 2,872 kg/day in 2006 and discharged loading is 11,818 kg/day and 722 kg/day in 2006 respectively. Discharged loadings were forecasted upward 1.0% of BOD and downward 2.7% of TP by 2013. The results of water quality prediction of Milyanggang 3 site were 1.6 mg/L of BOD and 0.120 mg/L of TP in 2013. It is over the target water quality at that site in 2015 about 6.7% and 20.0% respectively. Consequently, there need another counterplan to reduce the pollutants in that mid-watershed by 2015.

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In this study, it is an object to develop a regression model for the estimation of TOC (total organic carbon) concentration using investigated data for three years from 2010 to 2012 in the Gam Stream unit watershed, and applied in 2009 to verify the applicability of the regression model. TOC and CODMn (chemical oxygen demand) were appeared to be derived the highest correlation. TOC was significantly correlated with 5 variables including BOD (biological oxygen demand), discharge, SS (suspended solids), Chl-a (chlorophyll a) and TP (total phosphorus) of p<0.01. As a result of PCA (principal component analysis) and FA (factor analysis), COD, TOC, SS, discharge, BOD and TP have been classified as a first factor. TOCe concentration was estimated using the model developed as an independent variable BOD5 and CODMn. R squared value between TOC and measurement TOC is 0.745 and 0.822, respectively. The independent variable were added step by step while removing lower importance variable. Based on the developed optimal model, R squared value between measurement value and estimation value for TOC was 0.852. It was found that multiple independent variables might be a better the estimation of TOC concentration using the regression model equation(in a given sites).