Allyltrimethylsilane inspired allylation of acetals, ketals, aldehydes, and ketones comprises one of the most viable, significant and graceful methods for the formation of carbon–carbon bonds leading to stereochemical transformation.
An efficient andc onvenient synthesis of pyrrolo[1,2-a]quinoxalines from 1-(2-aminoaryl)pyrrole anda rylacetic acids has been described by using acombination of CuSO 4 as the catalysta nd 2,2'-bipyridyl ast he ligand in the presence of O 2 as an oxidant. The prominentf eatures of this method are the use of readily availablestarting materials, inexpensive catalyst, broad substrate scope and high product yields.
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