Molecules of bisthiolterthiophene have been adsorbed on the two facing gold electrodes of a mechanically controllable break junction in order to form metal-molecule(s)-metal junctions. Current-voltage (I-V) characteristics have been recorded at room temperature. Zero bias conductances were measured in the 10-100 nS range and different kinds of non-linear I-V curves with step-like features were reproducibly obtained. Switching between different kinds of I-V curves could be induced by varying the distance between the two metallic electrodes. The experimental results are discussed within the framework of tunneling transport models explicitly taking into account the discrete nature of the electronic spectrum of the molecule.Comment: 12 pages, 12 figures to appear in Phys. Rev. B 59(19) 199

Optical quantum communication utilizing satellite platforms has the potential to extend the reach of quantum key distribution (QKD) from terrestrial limits of ∼200 km to global scales. We have developed a thorough numerical simulation using realistic simulated orbits and incorporating the effects of pointing error, diffraction, atmosphere and telescope design, to obtain estimates of the loss and background noise which a satellite-based system would experience. Combining with quantum optics simulations of sources and detection, we determine the length of secure key for QKD, as well as entanglement visibility and achievable distances for fundamental experiments. We analyze the performance of a low Earth orbit (LEO) satellite for downlink and uplink scenarios of the quantum optical signals. We argue that the advantages of locating the quantum source on the ground justify a greater scientific interest in an uplink as compared to a downlink. An uplink with a ground transmitter of at least 25 cm diameter and a 30 cm receiver telescope on the satellite could be used to successfully perform QKD multiple times per week with either an entangled photon source or with a weak coherent pulse source, as well as perform long-distance Bell tests and quantum teleportation. Our model helps to resolve important design considerations such as operating wavelength, type and specifications of sources and detectors, telescope designs, specific orbits and ground station locations, in view of anticipated overall system performance.2. Photons undergo a rotation to simulate imperfectly aligned polarization optics, and appropriate losses are applied to the quantum channel.3. Photons are measured resulting in count rate statistics, with added noise accounting for background light and detector dark counts. A realistic detector efficiency is used.4. These statistics are taken in various loss and background count rate regimes to assess optimal and typical expected performance.

We describe the functionalization of single-wall carbon nanotubes (SWNTs) with 4-(2-trimethylsilyl)ethynylaniline and the subsequent attachment of a zinc-phthalocyanine (ZnPc) derivative using the reliable Huisgen 1,3-dipolar cycloaddition. The motivation of this study was the preparation of a nanotube-based platform which allows the facile fabrication of more complex functional nanometer-scale structures, such as a SWNT-ZnPc hybrid. The nanotube derivatives described here were fully characterized by a combination of analytical techniques such as Raman, absorption and emission spectroscopy, atomic force and scanning electron microscopy (AFM and SEM), and thermogravimetric analysis (TGA). The SWNT-ZnPc nanoconjugate was also investigated with a series of steady-state and time-resolved spectroscopy experiments, and a photoinduced communication between the two photoactive components (i.e., SWNT and ZnPc) was identified. Such beneficial features lead to monochromatic internal photoconversion efficiencies of 17.3% when the SWNT-ZnPc hybrid material was tested as photoactive material in an ITO photoanode.