Ruthenium imido complexes, [ ( T -C ~HMe 2), have been synthesised by the room temperature reaction of [(q-C6ti6)R~C12]2 with 2 equiv. of LiNH(2,6-R2C6H3) and 1 has been shown by single-crystal X-ray diffraction to be a symmetrical, imido-bridged dimer containing a bent Ru2N2 bridge.
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