RGB light emitting ZnSe based nanocrystals: ZnSe (blue), ZnSe:Cu (green) and ZnSe:Mn (red) were synthesized by capping the surface of the nanocrystals with oleic acid. The obtained nanocrystal powders were characterized by using XRD, HR-TEM, ICP-AES, FT-IR, and FT-Raman spectroscopies. The optical properties were also measured by UV/Vis and photoluminescence (PL) spectroscopies. The PL spectra showed broad emission peaks at 471 nm (ZnSe), 530 nm (ZnSe:Cu) and 665 nm (ZnSe:Mn), with relative PL efficiencies in the range of 0.7% to 5.1% compared to a reference organic dye standard. The measured average particle sizes from the HR-TEM images for those three nanocrystals were 4.5 nm on average, which were also supported well by the Debye-Scherrer calculations. The elemental compositions of the ZnSe based nanocrystals were determined by ICP-AES analyses. Finally, the drawn CIE diagram showed the color coordinates of (0.15, 0.16) for ZnSe, (0.22, 0.57) for ZnSe:Cu, and (0.62, 0.35) for ZnSe:Mn respectively, which were fairly well matched to that of the RGB color standards.

Free cooling system is used to reduce energy consumption of cooling system. Free cooling system is consisted of cooling group and dry-cooler in which heat exchange of chilled water and out air is conducted. Although this system has an excellent energy saving effect in place having cooling load regularly, data or material of design for free cooling system is lacked. In this study, characteristics analysis of free cooling system is conducted through software HYSYS with changing some facts. The main result is following as : Dry-cooler capacity is influenced by out air temperature, required chilled water temperature and LMTD(Logarithmic Mean Temperature Difference) of heat exchanger. As out air temperature is more low, dry-cooler capacity become increased. in addition, as required chilled water temperature is more high and LMTD is more low, the out air temperature range is widened for using dry-cooler. If out air temperature is below 0℃, antifreeze need to be used because freeze and burst can be occurred. In case of South Korea, antifreeze of 34% of ethylene glycol concentration is proper. When compressor load of R22, R134a and R407C is compared, considering environmental regulation and energy consumption, R134a is best working fluid.

t i o na mo u n to fS e o u li s1 1 %, C h u n c h e o ni s1 7 . 5 %, De a j e o n i s1 5 %,Ul s a n i s1 4 %.I n c a s eo fl a r g es c a l eo fa i r -c o n d i t i o n i n g ,i ti sr e a s o n a b l et ou s ef r e ec o o l i n g s y s t e m a l t h o u g ht h es y s t e m i su s e di nS e o u l Key Words： 프리쿨링 시스템( F r e ec o o l i n gs y s t e m) , 압축일량( C o mp r e s s o rwo r k ) , 드라이쿨러( Dr yc o o l e r ) , 에너지 절감( E n e r g yc o n s e r v a t i o n ) ,성능 분석( P e r f o r ma n c eAn a l y s i s ) ,HYS YS .

In this paper, among various systems applying hot-gas bypass control, outdoor temperature, outlet temperature of water cooler, superheating and subcooling degree, which are the factors affecting the performance of the system bypassing hot-gas to evaporator inlet were analyzed. The main results were summarized as following. Frist of all, performance of refrigeration system bypassing hot-gas to evaporator inlet was affected by outdoor temperature, outlet temperature of water cooler, superheating and sub cooling degree. Thus, providing basic planning date of refrigeration system obtained through optimization of variables is expectable. Thus, providing the basic design data of refrigeration system can be offered by performing the optimization of these variables. Also, the feasibility of this refrigeration system proposed in this paper was obtained by analyzing operating characteristics of the system bypassing hot-gas to evaporator inlet.