This article presents an original work aiming at kinetically surveying the substrate‐selective mechanism from a molecularly imprinted polymer. With Bisphenol A (BPA) as the template, the imprinted polymer was prepared. The result indicates that the imprinted polymer presents a much more complicated sorption toward the template than toward its analogue. The rate constant in the case of the template appears to be a function of coverage degree. There are also significant deviations from the idealized Langmuir model. Related information indicates that these logically can be a result from the induced molecular memory within the binding framework, which makes the polymer capable of selectively adsorbing the imprint species.

The strategy allows the enantioselective synthesis of a variety of target compounds with a stereogenic quaternary carbon center. An application of the procedure is represented in the synthesis of (S)-convolutamydine A (V). -(CHEN, J.-R.; LIU, X.-P.; ZHU, X.-Y.; LI, L.; QIAO, Y.-F.; ZHANG, J.-M.; XIAO