We herein report a rigid nested metal-organic framework (MOF) featuring a unique thermoresponsive gating adsorption behavior, which, in contrast to any known flexibility modes for stimuli-responsive MOFs, depends on the thermal motion of the extra-framework counterions. In addition, this MOF also exhibits adsorption selectivity of CO over N , H , and Ar at 273 K, thus enabling a strategic separation and encapsulation of CO .

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We proposed a new kind of TFT using organic–inorganic hybrid perovskite CH3NH3PbI3 material as the semiconducting channel.

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