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The YAG: Eu 3+ fluorescent glass for NUV(near ultraviolet) white LEDs was obtained firstly by synthesizing Y 3 Al 5 O 12 (YAG): Eu 3+ precursors through a simple co-precipitation method, and then mixing precursor with B 2 O 3 -Al 2 O 3 -SiO 2 -Na 2 O-BaO glass powder calcined at 1400°C for 2.5 hours. The as-prepared YAG glass-ceramic phosphor was investigated by DTA, XRD, SEM, and photoluminescence (PL). Influence of YAG: Eu 3+ precursor and Eu 3+ doping on excitation and emission spectra also have been studied. The results show that: the phosphor's emission peak located at 393nm is correspond to the 7 F 0 - 5 L 6 transition of Eu 3+ ions, which matches good with UV LED chips; the phosphor gives intense emission at 593nm originating from the 5 D 0 - 7 F 1 transition of Eu 3+ ions. When the YAG precursor is 0.9g and amount of Eu 3+ doped is 0.08, the fluorescence excitation spectra of glass and emission spectra of the peak intensity reach its maximum value. The YAG: Eu 3+ fluorescence glass could be a promising material for the production of near ultraviolet chip white light-emitting diode.