The ever-increasing amount of anthropogenic carbon dioxide (CO2) emissions has resulted in great environmental impacts, the heterogeneous catalysis of CO2 hydrogenation to methanol is of great significance.

Melt derived 45S5 Bioglass(R) has been studied for more than 25 years. Bioglass(R) has excellent biocompatibility, and its surface reactivity has contributed to its clinical success over the past 10 years. Recently, porous bioactive glasses have been derived through sol-gel processing in an attempt to increase the specific surface area, and, thus, the surface reactivity and degradability of the material. This allows the material to be replaced ultimately by natural tissue while it stimulates bone regeneration. In this work, the processing and properties of these sol-gel bioactive glasses are discussed, and a new drying method and treatment is described to make homogeneous particulate and monoliths on a production scale.

The efficient utilization of biomass, the only globally available, renewable and abundant carbon-neutral source, is of high significance in green and sustainable chemistry. Polyoxometalates (POMs) and POM-based composites have been...