Whey protein isolate (WPI) fibrils were prepared using an acid hydrolysis induction process. Carbon nanotubes (CNTs) and carbon nano-onions (CNOs) were made via the catalytic chemical vapor deposition (CVD) of methane. WPI fibril–CNTs and WPI fibril–CNOs were prepared via hydrothermal synthesis at 80 °C. The composites were characterized by SEM, TEM, FTIR, XRD, Raman, and TG analyses. The interplay between WPI fibrils and CNTs and CNOs were studied. The WPI fibrils with CNTs and CNOs formed uniform gels and films. CNTs and CNOs were highly dispersed in the gels. Hydrogels of WPI fibrils with CNTs (or CNOs) could be new materials with applications in medicine or other fields. The CNTs and CNOs shortened the WPI fibrils, which might have important research value for curing fibrosis diseases such as Parkinson’s and Alzheimer’s diseases. The FTIR revealed that CNTs and CNOs both had interactions with WPI fibrils. The XRD analysis suggested that most of the CNTs were wrapped in WPI fibrils, while CNOs were partially wrapped. This helped to increase the biocompatibility and reduce the cytotoxicity of CNTs and CNOs. HR-TEM and Raman spectroscopy studies showed that the graphitization level of CNTs was higher than for CNOs. After hybridization with WPI fibrils, more defects were created in CNTs, but some original defects were dismissed in CNOs. The TG results indicated that a new phase of WPI fibril–CNTs or CNOs was formed.

As the depth of coal mining increases, rockbursts become more severe, and multiple rockburst accidents have previously occurred, seriously affecting coal mine production safety. With the Hegang mining area as the research object and using field measurement and numerical simulation as the research methods, the geological and tectonic characteristics of each impact mine in the Hegang mining area are analyzed to obtain the tectonic stress field distribution characteristics of each mine and the tectonic stress field distribution trend in the Hegang mining area. The maximum horizontal principal stress and the minimum horizontal principal stress on the energy field in the overrun area of the retrieval working face is analyzed via numerical simulation, and the influence trend of the ground stress on the impact ground pressure is finally obtained. Results show that using the typical working face where rockburst occurs as the geological proto-type, the influence of the direction of the ground stress field, the maximum horizontal principal stress and the minimum horizontal principal stress on the energy field in the overrun area of the retrieval working face is analyzed via numerical simulation, and the influence trend of the ground stress on the impact ground pressure is finally obtained. When the angle is 70°~90°, an energy peak in the overrun area of the working face reaches its maximum. The ratio of the minimum horizontal stress to the vertical stress is positively correlated with the energy concentration in the overrun area of the working face, but its change has a minimal effect on the energy distribution in the overrun area of the working face. When this ratio is increased from 0.6 to 1.4, the peak energy of the simulated working face only increases by 8.22%, and the energy concentration area remains basically unchanged.

In order to research on the law of methane released through the pore in coal particles, the methane desorption experiments were conducted, respectively, on four types of particle size of coal samples under three different initial adsorption pressures. The cumulative methane desorption quantity (CMDQ) with time increasing was obtained to show that the reciprocal of CMDQ was in linear relation with the reciprocal of the square root of time, and the correlation coefficients were all above 0.99, on basis of which an empirical formula of CMDQ was established. Then, according to Fick diffusion law and Darcy percolation law, the mathematical models of methane emission from the spherical coal particles were created, respectively, and the corresponding calculating software was programmed by the finite difference method to obtain the simulated CMDQ of each sample under different conditions. The methane emission rate functions (MERF) of the simulation and the experiment were also calculated, respectively. Comparative analysis between the numerically simulated outcomes and the assay results reveals that the simulation outcomes as per Darcy’s law match the experimental data better, while the simulated results by Fick’s law deviate greatly, which indicates that the methane flowing through coal particles is more in accordance with Darcy’s law.