The confined crystallization behavior, melting behavior, and nonisothermal crystallization kinetics of the poly(ethylene glycol) block (PEG) in poly(L-lactide)poly(ethylene glycol) (PLLA-PEG) diblock copolymers were investigated with wideangle X-ray diffraction and differential scanning calorimetry. The analysis showed that the nonisothermal crystallization behavior changed from fitting the Ozawa equation and the Avrami equation modified by Jeziorny to deviating from them with the molecular weight of the poly(L-lactide) (PLLA) block increasing. This resulted from the gradual strengthening of the confined effect, which was imposed by the crystallization of the PLLA block. The nucleation mechanism of the PEG block of PLLA15000-PEG5000 at a larger degree of supercooling was different from that of PLLA2500-PEG5000, PLLA5000-PEG5000, and PEG5000 (the numbers after PEG and PLLA denote the molecular weights of the PEG and PLLA blocks, respectively). They were homogeneous nucleation and heterogeneous nucleation, respectively. The PLLA block bonded chemically with the PEG block and increased the crystallization activation energy, but it provided nucleating sites for the crystallization of the PEG block, and the crystallization rate rose when it was heterogeneous nucleation. The number of melting peaks was three and one for the PEG homopolymer and the PEG block of the diblock copolymers, respectively. V V C 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: [3215][3216][3217][3218][3219][3220][3221][3222][3223][3224][3225][3226] 2006

The Advanced Space-based Solar Observatory (ASO-S) is a mission proposed for the 25th solar maximum by the Chinese solar community. The scientific objectives are to study the relationships between the solar magnetic field, solar flares and coronal mass ejections (CMEs). Three payloads are deployed: the Full-disk vector MagnetoGraph (FMG), the Lyman-α Solar Telescope (LST) and the Hard X-ray Imager (HXI). ASO-S will perform the first simultaneous observations of the photospheric vector magnetic field, non-thermal imaging of solar flares, and the initiation and early propagation of CMEs on a single platform. ASO-S is scheduled to be launched into a 720 km Sun-synchronous orbit in 2022. This paper presents an overview of the mission till the end of Phase-B and the beginning of Phase-C.