The homogeneous rare-earth catalytic system was used to initiate the polymerization of isoprene, and a novel IR was synthesized with high molecular weight and narrow molecular weight distribution. According to the self-developed rare-earth IR properties, a study on IR and IR/NR blend was made. Microstructure and molecular characteristics of JiHua rare-earth IR were identified by IR spectra, 13C NMR and GPC, and the effect of JiHua rare-earth IR on the vulcanization characteristics and dynamic properties in IR/NR blend was investigated and compared with IR (SKI-3) synthesized with titanium catalyst system and rare-earth isoprene rubber (SKI-5) made in Russia. The results showed that JiHua rare-earth IR to be developed independently was a novel synthetic rubber with excellent comprehensive performance, and it can be used independently and partly substitute natural rubber to make tire. In the IR/NR blend, Not only vulcanization characteristics and the safety in operation for NR was greatly improved, But also dynamic properties of vulcanizates such as dynamic cutting resistance, abrasion resistance, wet-skid resistance and aging resistance were improved to different degrees. These properties reach or surpass the level of the foreign similar products like Russia SKI-3 and Russia SKI-5.
The homogeneous rare earth IR/NR blend applied in tread compound of all-steel TBR tire was investigated,and compare to Russian SKI-3, SKI-5/NR blends and NR.The results showed homogeneous rare earth IR/NR blend had similar vulcanization characteristics, dynamic mechanical properties and heat-aging resistance or even better. It was inspected that the appearance, balance, air bubbles, X-ray and homogeneity inspection test of the tires produced by homogeneous rare earth IR/NR blend by the tire factory,all the indicators were qualified. The tires passed the China National Quality Supervision and Inspection Center of rubber tire certification. The tires met the requirements of all-steel TBR tire.The homogeneous rare earth IR prepared by Petro China Jilin Petrochemical Company could 40 phr instead of NR using in tread compound of all-steel TBR tire,which could extend tire life and reduce tire material costs.
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