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Back cover image: The electrochemical CO2 reduction (eCO2R) to value‐added fuels and chemicals by using renewable electricity provides a cleaner and more sustainable route with economic benefits. In article number https://doi.org/10.1002/cey2.87, Jinli Qiao et al. review the recent progress of the activity, product selectivity and stability in carbon‐based metal‐free catalysts. The key challenges and future potential approaches for efficient eCO2R to low carbon‐based fuels are highlighted. The role of electrolytes, electrochemical cells design and evaluation, product selectivity and structural composition are also mentioned.

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