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The discovery of a new Co-catalyzed hydrogen atom transfer (HAT) C(sp3)-C(sp2) bond cleavage method to access ketones from alkenes is reported. This unprecedented transformation features mild reaction conditions and good...

A nickel-catalysed reductive cross-coupling between 2-bromo cycloalkenyl carboxylic acids and alkyl bromides has been developed, affording all-carbon tetrasubstituted cycloalkenes in moderate to excellent yields up to 92%. Mechanistic studies indicated...