The electronic and optical properties of zinc-blende (zb) GeC have been investigated using first principles calculations based on the density functional theory (DFT). The obtained band gap of zb-GeC is 2.30 eV by means of Heyd-Scuseria-Ernzerhof (HSE) functional. We have discussed the energy-dependent optical functions including dielectric constants, refractive index, absorption, reflectivity, and energy-loss spectrum in detail. The results reveal that zb-GeC has a higher static dielectric constant compared with that of zb-SiC. The optical functions are mainly associated with the interband transitions from the occupied valence bands (VBs) Ge 4p and C 2p states to Ge 4s, 4p and C 2p states of the unoccupied conduction bands (CBs).
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