Co3O4-modified CeO2 (Co/Ce 1:4) was prepared by a combination of sol–gel processing and solvothermal treatment. The distribution of Co was controlled by means of the synthesis protocol to yield three different morphologies, namely, Co3O4 nanoparticles located on the surface of CeO2 particles, coexistent Co3O4 and CeO2 nanoparticles, or Co oxide structures homogeneously distributed within CeO2. The effect of the different morphologies on the properties of Co3O4–CeO2 was investigated with regard to the crystallite phase(s), particle size, surface area, and catalytic activity for CO oxidation. The material with Co3O4 nanoparticles finely dispersed on the surface of CeO2 particles had the highest catalytic activity.
ZnTiO 3 was synthesized by sol-gel processing using a single-source precursor in which the two metal atoms are linked by means of p-carboxybenzaldehyde oxime. According to spectroscopic investigations, the COOH group is coordinated to Zn 2+ and the oximate group to a Ti(OiPr) 3 moiety. The temperature-dependent structure evolution of ZnTiO 3 was investigated to illustrate the advantage of this approach compared to materials prepared from two individual precursors (zinc benzoate and oximate-modified Ti(OiPr) 4 ). ZnTiO 3 prepared from the single-source precursor has a more homogeneous structure through all stages of the synthesis process and a higher surface area. The latter results in a higher activity in the photocatalytic degradation of methylene blue.
Chinese mahogany (Toona sinensis) is a woody plant that is widely cultivated in China and Malaysia. Toona sinensis is important economically, including as a nutritious food source, as material for traditional Chinese medicine and as a high‐quality hardwood. However, the absence of a reference genome has hindered in‐depth molecular and evolutionary studies of this plant. In this study, we report a high‐quality T. sinensis genome assembly, with scaffolds anchored to 28 chromosomes and a total assembled length of 596 Mb (contig N50 = 1.5 Mb and scaffold N50 = 21.5 Mb). A total of 34,345 genes were predicted in the genome after homology‐based and de novo annotation analyses. Evolutionary analysis showed that the genomes of T. sinensis and Populus trichocarpa diverged ~99.1–103.1 million years ago, and the T. sinensis genome underwent a recent genome‐wide duplication event at ~7.8 million years and one more ancient whole genome duplication event at ~71.5 million years. These results provide a high‐quality chromosome‐level reference genome for T. sinensis and confirm its evolutionary position at the genomic level. Such information will offer genomic resources to study the molecular mechanism of terpenoid biosynthesis and the formation of flavour compounds, which will further facilitate its molecular breeding. As the first chromosome‐level genome assembled in the family Meliaceae, it will provide unique insights into the evolution of members of the Meliaceae.
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