Several binuclear vanadium complexes were synthesized and investigated as catalysts for ethylene (co)polymerization. Under the activation of Et2AlCl, the binuclear vanadium complexes exhibited higher activities than mononuclear analogues in ethylene...
Vanadium complex containing bulky ligand were investigated for the allene polymerization. Such complexes exhibited distinguished 2,3-selectivity (>99 %) for phenylallene (PA) polymerization which were proved by the corresponding NMR spectra....
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