Polystyrene (PS) microgel colloids have often been used successfully to model hard sphere behaviour even though the term "gel" invokes inevitably the notion of a more or less soft, deformable object. Here we systematically study the effect of reducing the cross-link density from 1 : 10 (1 cross-link per 10 monomers) to 1 : 100 on particle interactions and "softness". We report on the synthesis and purification of 1 : 10, 1 : 25, 1 : 50, 1 : 75 and 1 : 100 cross-linked PS particles and their characterization in terms of single particle properties, as well as the behaviour of concentrated dispersions. We are able to tune particle softness in the range between soft PNiPAM-microgels and hard PMMA particles while still allowing the mapping of the microgels onto hard sphere behavior with respect to phase diagram and static structure factors. This is mainly due to a rather homogeneous radial distribution of cross-links in contrast to PNiPAM microgels where the cross-link density decreases radially. We find that up to a cross-link density of 1 : 50 particle form factors are perfectly described by a homogeneous sphere model whereas 1 : 75 and 1 : 100 cross-linked spheres are slightly better described as fuzzy spheres. However the fuzziness is rather small compared to typical PNiPAM microgels so that a hard sphere mapping still holds even for these low cross-link densities. Finally, by varying the reaction conditions - changing from batch to semibatch emulsion polymerization and varying the feed rate or by adjusting the monomer to initiator ratio we can tune the fuzziness or significantly alter the inner structure to a more open, star-like architecture.

While microgels are in general described as soft particles, polystyrene (PS) microgels can be synthesized in a way that cross-link density has only a minor influence on their physical properties. Even though the particles swell in a good solvent, the imparted slight softness still allows a mapping on hard sphere behaviour for a large range of cross-link densities [Schneider et al., Soft Matter, 2017, 13, 445]. Nevertheless, the hard sphere analogy breaks down as soon as polymer chains are added to these systems. Quantitative differences between PS microgels and true hard sphere systems appear and the differences between stronger and weaker cross-linked PS microgels can be observed. To gain deeper insights into the origin of these deviations from true hard sphere behaviour, this work is addressed to a systematic study of the colloid-polymer interactions in PS microgel-polymer mixtures. We investigated the aggregation behaviour (namely aggregation concentration and cluster structure) as a function of colloid size, cross-link density and colloid-polymer size ratio in very dilute colloidal suspensions. Our results show that the interplay of cross-link density and polymer size is a key parameter for the strength of the colloid-polymer interactions. Furthermore, the centre-to-centre distance of the colloidal particles in the formed clusters decreases if the cross-link density is decreased, allowing for a higher packing density. This may also explain the unusually high fluid packing fractions observed in the re-entry region of the phase diagram of PS microgel-free PS polymer mixtures.

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