We report on an investigation of quasi-free-standing graphene on 6H-SiC(0001)
which was prepared by intercalation of hydrogen under the buffer layer. Using
infrared absorption spectroscopy we prove that the SiC(0001) surface is
saturated with hydrogen. Raman spectra demonstrate the conversion of the buffer
layer into graphene which exhibits a slight tensile strain and short range
defects. The layers are hole doped (p = 5.0-6.5 x 10^12 cm^(-2)) with a carrier
mobility of 3,100 cm^2/Vs at room temperature. Compared to graphene on the
buffer layer a strongly reduced temperature dependence of the mobility is
observed for graphene on H-terminated SiC(0001)which justifies the term
"quasi-free-standing".Comment: 3 pages, 3 figures, accepted for publication in Applied Physics
Letter
We investigate the transport properties of high-quality single-layer graphene, epitaxially grown on a 6H-SiC͑0001͒ substrate. We have measured transport properties, in particular charge-carrier density, mobility, conductivity, and magnetoconductance of large samples as well as submicrometer-sized Hall bars which are entirely lying on atomically flat substrate terraces. The results display high mobilities, independent of sample size. The temperature dependence of the conductance indicates a rather strong coupling to the SiC substrate. An analysis of the Shubnikov-de Haas effect yields the Landau-level spectrum of single-layer graphene. When gated close to the Dirac point, the mobility increases substantially and the graphenelike quantum Hall effect occurs.
We investigate the magnetotransport in large area graphene Hall bars epitaxially grown on silicon carbide. In the intermediate field regime between weak localization and Landau quantization, the observed temperature-dependent parabolic magnetoresistivity is a manifestation of the electron-electron interaction. We can consistently describe the data with a model for diffusive (magneto)transport that also includes magnetic-field-dependent effects originating from ballistic time scales. We find an excellent agreement between the experimentally observed temperature dependence of magnetoresistivity and the theory of electron-electron interaction in the diffusive regime. We can further assign a temperature-driven crossover to the reduction of the multiplet modes contributing to electron-electron interaction from 7 to 3 due to intervalley scattering. In addition, we find a temperature-independent ballistic contribution to the magnetoresistivity in classically strong magnetic fields.
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