The complexes [ L2 M n11I 2 ( 1.1-0 ) ( p-M eC02 12] ( C 104)2, ( 1 1, a n d [ L'2 M n11I 2 ( p-0 ) ( p-M eC O2 1 2] (C I 04) 2-H 20, (21, where L and L' represent the cyclic triamines 1,4,7-triazacyclononane and (N,N',N"-trimethyl-1,4,7-triazacyclononane, have been synthesized from Mn( MeC02)3.2H20 in water-ethanol mixtures; characterization by X-ray crystallography showed that both complexes contain a p-0x0-di-p-acetato-metal(l11) core, as found in hemerythrin, and therefore these complexes may have bioinorganic significance.
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