We prepared synthetic hydroxyapatite [HAP; Ca5(PO4)(3-x)(CO3)x(OH)(1+x) (x = 0.3)] and then investigated this material's ability to remove trivalent antimony [Sb(III)] from water. The HAP was characterized by X-ray diffraction analysis, scanning electron microscopy, X-ray energy dispersive spectroscopy, X-ray photoelectron spectroscopy, and infrared spectroscopy. The sorption of Sb(III) to HAP was measured over an Sb(III) concentration range of 0.05-50 mg L(-1), at constant ionic strength (I = 0.01 mol dm(-3)) in equilibrated aqueous suspensions (34 g dm(-3)) for 5 < pH < 8 in vessels that were closed to the atmosphere. Under these conditions, we found that HAP particles were enriched in Ca after incongruent dissolution of the solid. More than 95% of the Sb(III) in solution adsorbed to the solid-phase HAP in <30 min. The equilibrium distribution of Sb(III) (solid vs liquid phase) was characterized by a Langmuir model with gamma(max) = 6.7 +/- 0.1 x 10(-8) mol m(-2) (1.4 +/- 0.2 x 10(-4) mol dm(-3) g(-1)) and K(ads) = 1.5 +/- 0.2 x 10(3) dm3 mol(-1). As Sb adsorption occurred, the pH of the isoelectric point (pH(iep)) of the HAP suspensions declined from 7.7 to 6.9. This finding supports the idea that the negative surface potential of the HAP increased due to the adsorption of Sb as a charged species. The decline in pH(iep) during Sb adsorption plus the thermodynamic description of the Sb(III)-HAP-H2O system suggest likely surface reactions for the interaction of Sb with HAP. We discuss the efficiency of Sb removal from water by HAP in the context of phosphate enrichment.

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A four-step chemical sequential extraction procedure was used to evaluate the distribution of Al, As, Cr, Cu, Fe, Mn, Ni, Pb, Ti, V and Zn in airborne particulate matter collected on glass fibre filters using a high-volume sampler. Two sets of samples were collected in 2001 (winter and summer campaigns) in representative zones of an industrial city of Argentina. The leaching scheme was applied to PM-10 particles and consisted in extracting the elements in four fractions, namely soluble and exchangeable elements; carbonates, oxides and reducible elements; bound to organic matter and sulfidic metals; and residual elements. Metals and metalloids at microg g(-1) level were determined in each fraction by inductively coupled plasma optical emission spectrometry (ICP OES). Analyte concentration varied from 14 microg g(-1) (equivalent to 1.0 ng m(-3)) for As to 11.8 mg g(-1) (equivalent to 2,089 ng m(-3)) for Al. Seven elements, namely Al, Cr, Fe, Mn, Pb, Ti and Zn showed similar distributions in both seasons while As was distributed in a significantly different manner in each season. The results exhibited low As contents in the first and second fractions that could be associated with routine coal combustion and a high content in the third and fourth fractions of the summer samples that could be linked to the use of pesticides. Aluminium, As, Cu, Mn, Ni, Ti, V and Zn were found in different percentages in the more bioavailable aqueous fraction with As, Mn, V and Zn exhibiting solubilities greater than 1% while Cr and Pb being insoluble. The content of Al, Cr, Cu, Fe, Ni, Pb, and Zn in the residual fraction was, in average, higher than 50%. A comparative assessment of the use of the underlying information available from fractionation studies compared to that obtained from total element content was done for Fe and Mn. It showed that the results obtained using chemical sequential extraction procedures allowed further discrimination of the potential air pollution sources.

An on-line nickel preconcentration system implemented with chemical vapor generation associated to inductively coupled plasma optical emission spectrometry (VG-ICP-OES) was studied. Trace amounts of nickel were preconcentrated by sorption on a minicolumn packed with activated carbon at pH 5.0. The analyte retained was removed from the minicolumn with 0.3 mol l À1 hydrochloric acid. After that, volatile species of nickel were generated by merging the acidified sample and sodium tetrahydroborate(III) in a continuous flow system. The gaseous analyte was subsequently introduced via a stream of Ar carrier into the inlet tube of the inductively coupled plasma torch. For the preconcentration procedure, an enrichment factor of 36-fold for a sample volume of 25 ml was obtained. The detection limit (DL) obtained was 0.06 mg l À1 . The precision (RSD) for ten replicate determinations at a level of 0.5 mg l À1 was 4.0%. Potential interfering effects on the Ni signal were examined.