Table 1. Data for Br -, NH 3 and Br --NH 3 at MP2/aug-cc-pVDZ and MP2/aug-cc-pVTZ levels. Listed are optimized internal coordinates (r in Å, θ in degrees), harmonic vibrational frequencies (ω in cm -1 , intensities in km/mol in brackets), zpe (in kcal/mol), electronic energies (E in au), dissociation energy (D 0 in cm -1 ), and enthalpy change for association reaction at 298K (

Abstract. Positively charged helium droplets were produced by ionization of liquid helium in an electrostatic spraying experiment, in which fluid emerging from a thin glass capillary was ionized by applying a high voltage to a needle inside the capillary. At 2.2 K, fine droplets (<10 µm in diameter) were produced in pulsed sprays or showers with total currents as high as 0.4 µA at relatively low voltages (2-4 kV). Ionization was accompanied by a visible glow at the needle and glass tips. Droplet formation was suppressed at 3.5 K. In contrast, liquid nitrogen formed a well-defined Taylor cone with droplets having diameters comparable to the jet (≈100 µm) at much lower currents (3 nA) and higher voltages (9 kV), in agreement with previous results. The mechanism for charging in these liquids was proposed to be field ionization, identical to the processes leading to conduction in cryogenic insulating liquids observed by Gomer. The high currents resulting from field ionization in helium, together with the intrinsically low surface tension of helium I, led to charge densities that greatly exceeded the Rayleigh limit, thus preventing formation of a Taylor cone and resulting in Coulomb explosion of the liquid.