Phenylacetonitrile and its derivatives were treated with alcohols in the presence of potassium iodide and iodine affording the corresponding benzoate esters via degradation, oxidation and esterification under mild conditions. The products were characterised by IR, 1H NMR, MS and elemental analysis.
The professional and technical talents are the significant supporting factor for the leapforward development of economy and society, for the timely-completed political task of overcoming poverty and for the overall construction of moderately prosperous society in all aspects during the period of Five-Year Plan. Therefore, it is particularly urgent for Guizhou Province to study the scale of professional and technical talents due to the change of development strategy. In this study, based on the development of professional and technical personnel in Guizhou. The study constructed the forecast model, which is the combination of regression model and gray model. Besides, the study tried to circumvent the inherent limitations of single forecasting model with the purpose of improving the accuracy and scientific of forecasting, inspiring and enlightening the scientific development of Guizhou Province.
Carboxylic acid esters Q 0530Carbon-Carbon Bond Cleavage and Esterification of Phenylacetonitrile and Its Derivatives Affording the Corresponding Benzoic Esters. -The electronic effect of phenylacetonitrile substituents is remarkably; the reactivity of saturated alcohols is described to follow the sequence of primary, secondary, tertiary due to the steric-hindrance effect. -(WANG, Z.; KANG, J.; YU*, M.; J. Chem. Res. 2007, 6, 323-324;
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.