Eight transition metal complexes of various Schiff bases supported on poly(vinyl chloride) (PVC) were prepared and characterized. These metal complexes were screened as heterogeneous catalysts in the synthesis of b-amino alcohols by ring opening of epoxides with amines. The best catalyst was identified as a Ni(II) complex of PVC-supported 2-[(2-aminoethylimino)methyl]phenol and it was used in the synthesis of a number of different b-amino alcohols. The catalyst was found to be reusable for up to five cycles.

A Ni(II) complex of PVC‐supported 2‐[(2‐aminoethylimino)methyl]phenol is found to be a highly effective catalyst in the synthesis of β‐amino alcohols by ring opening of epoxides with amines.