We successfully designed Zn ion doped ZSM-5/silicalite-1 core-shell zeolite catalyst. On methanol to para-xylene (MTpX) over the core-shell catalyst, p-xylene yield was 40.7 C-mol% and para-selectivity (para-xylene selectivity in xylene isomers) was higher than 99 C-mol%, which substantially exceeds the other results reported in the literature.
Over 65% yield of 5-hydroxymethylfurfural from glucose was obtained under mild condition by using ZSM-5/HT composite as acid/base bifunctional catalyst.
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