Kalyan K. Paul scite author profile

2009) Micelle catalyzed oxidation of propan-2-ol to acetone by penta-valent vanadium in aqueous acid media, Vanadium (V) oxidation of propan-2-ol shows a first-order dependency on the concentrations of propan-2-ol, vanadium (V), H þ and HSO À 4 . These observations remain unaltered in the presence of externally added surfactant. The effects of the cationic surfactant (i.e. CPC), anionic surfactant (i.e. SDS) and neutral surfactant (i.e. TX-100) have been studied. CPC inhibits the reactions whereas SDS and TX-100 accelerate the reaction to different extents. Observed effects have been explained by considering the hydrophobic and electrostatic interactions between the surfactants and reactants. SDS and TX-100 can be used as catalysts in the production of acetone from propan-2-ol.

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Kinetics and Mechanism of 2,2’-Bipyridyl Promoted Chromic Acid Oxidation of Ethanol and Propan-1-ol in Aqueous Micellar Media~!2008-08-15~!2008-09-26~!2008-11-14~!

Mandal¹,

Chowdhury²,

Paul³

et al. 2008

TOCATJ

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Kalyan K. Paul

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Micelle catalyzed oxidation of propan-2-ol to acetone by penta-valent vanadium in aqueous acid media

Kinetics and Mechanism of 2,2’-Bipyridyl Promoted Chromic Acid Oxidation of Ethanol and Propan-1-ol in Aqueous Micellar Media~!2008-08-15~!2008-09-26~!2008-11-14~!

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