Quebracho tannin wood adhesive in non-formaldehyde approach has low hardening rate and needs more pressing time than formaldehyde-based wood adhesives during wood composites production. In this study, boric acid (BA) was used to increase autocondensation rate of tannin to make poplar plywood. The main ingredients of the adhesives included quebracho tannin, NaOH, hexamine, BA and polymeric isocyanate (PMDI). Thermomechanical analysis of without BA adhesives showed that maximum modulus of elasticity increased with increasing the initial tannin concentration from 40% to 50% (w/w), while no significant effect has been found by adding PMDI. Moreover, the addition of BA lowered time and temperature of hardening and increased modulus of elasticity of the adhesive. Also, tensile shear strength increased significantly with increasing the tannin concentration and the BA content (from 2% to 4%).Interestingly, applied BA in the glueline not only improved bonding quality of the panels, but also provided good preservative performance against fungal attack even after mild leaching test.
The cambium dynamics and wood formation of Oriental beech (Fagus orientalis Lipsky) was investigated during the 2008 growing season in the Nowshahr Hyrcanian forest, Iran (36°N, 51°E). Three study sites were selected along an altitudinal gradient (650, 1,100 and 1,600 m a.s.l.), and cambial activity rates of cell formation and cell maturation were studied on micro-cores collected in intervals of 10-20 days. The cambium reactivation of the low-altitude (L) and mid-altitude (M) trees occurred contemporaneously in late March, and also the consecutive phases of cell differentiation took place almost at the same time; however, the entry into cambial dormancy varied considerably from late August to mid-November. Due to lower temperature, the upper-altitude (U) trees showed a 10-day delay in their cambium reactivation, an earlier entry into cambium dormancy (mid-September) and a slower growth rate resulting in narrower tree rings. Despite these differences, the daily increment rates of the trees at all sites reached maximum values coincidently in the early June. Since the photoperiod is the only common external factor among different sites, it is concluded that the timing of the highest growth rate is controlled by the photoperiod.
Trees can control their shape and resist gravity thanks to their ability to produce wood under tensile stress. This stress is known to be produced during the maturation of wood fibres but the mechanism of its generation remains unclear. This study focuses on the formation of the secondary wall in tension wood produced in artificially tilted poplar saplings. Thickness of secondary wall layer (SL) and gelatinous layer (GL) were measured from cambium to mature wood in several trees sampled at different times after tilting. Measurements on wood fibres produced before tilting show the progressive increase of secondary wall thickness during the growing season. After the tilting date, SL thickness decreased markedly from normal wood to tension wood while the total thickness increased compared to normal wood, with the development of a thick GL. However, even after GL formation, SL thickness continues to increase during the growing season. GL thickening was observed to be faster than SL thickening. The development of the unlignified GL is proposed to be a low cost, efficient strategy for a fast generation of tensile stress in broadleaved trees.
International audienceVibrational properties of wood are affected by several parameters, of which extractives can be one of the most important ones. Wood for European musical instruments has been often studied, but traditional Middle Eastern ones had been left unnoticed. In this study white mulberry (Morus alba L.), the main material for long-necked lutes in Iran, was extracted by five solvents of various polarities (water included). Free-free bar forced vibrations were used to measure longitudinal (L) loss tangent (tanδ), storage (elastic) modulus (E′) and specific modulus (E′/γ) in the acoustic range. Their anisotropy between the 3 axes of orthotropy was determined by DMA (dynamic mechanical analysis). Native wood had a quite low EL′/γ but its tanδ was smaller than expected, and the anisotropy of tanδ and E′/γ was very low. Removal of extractives caused tanδ to increase and moduli to decrease. Acetone, the most effective solvent on damping despite a moderate extraction yield, increased tanδL by at least 20% but did not modify E′/γ as much. When used successively, its effects masked those of solvents used afterwards. Anisotropy of E′/γ was nearly unchanged after extraction in methanol or hot water, while tanδ was much more increased in R than in T direction. Results suggest that in white mulberry, damping is governed more by nature and localization of extractives rather than by their crud abundance
Vessel features of broadleaf trees may contain information about both spatial and temporal variations of environmental conditions. We report quantitative data about annual vessel characteristics for Oriental beech (Fagus orientalis Lipsky) in the Caspian forest in the Alborz Mountains, northern Iran. Time series of tree-ring width and of various vessel variables were constructed over a 50-year period for three sites along an altitudinal gradient from 1260 to 2200 m a.s.l. We evaluated the dependencies between ring width and vessel variables and estimated the influence of altitude and climate on these variables.Mean ring width and average vessel-lumen area decreased towards the high-elevation site whereas total vessel-lumen area was independent from altitude, and vessel density increased. Above-average warm summer and autumn seasons in the year prior to growth were negatively correlated with ring width and average vessel-lumen area whereas precipitation in the current June showed a positive association; vessel density responded exactly opposite to these climatic variables. Total vessel-lumen area was the only variable that reacted differently from site to site, mainly positively to temperature at 1200 m a.s.l. and negatively at 2000 and 2200 m a.s.l., whereas a consistent response to precipitation was lacking. The results indicate that vessel variables are meaningful indicators of changes in dynamics of wood formation in relation to climate along an altitudinal gradient in the Caspian mountains. As for climate reconstruction, we have to conclude that for our study area, vessel variables do not add much to information derived from ring width.
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