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Studies on the oxidation of α-olefins via the two-stage method are presented. The new method consisted of oxidizing C30+ α-olefins with hydrogen peroxide (2 equiv.) and subsequent oxidation with oxygen. Products with high acid numbers (29–82 mgKOH/g) and saponification numbers (64–140 mgKOH/g) were obtained and compared with products obtained using only hydrogen peroxide or oxygen. It was demonstrated that H2O2 can be partially replaced by oxygen in the oxidative cleavage reaction of α-olefins. N-hydroxyphthalimide in combination with Co(acac)2 demonstrated high activity in the oxidation stage using oxygen.

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In this study, the transition metal (Co (II), Cu (II), and Mn (II)) salts of carboxylated carbon nanotubes were synthesized and characterized (the determined metal contents were in the range of 0.89–1.16%). The catalytic activity and the possibility for recovery and reuse of the obtained heterogeneous salts were then studied in the solvent-free oxidation of ethylbenzene with oxygen. The oxidation processes were carried out at 80 °C under atmospheric pressure in the presence of N-hydroxyphthalimide. The highest conversion of ethylbenzene, 27%, was obtained with a system consisting of the Cu (II) salt of the carboxylated carbon nanotubes, N-hydroxyphthalimide, and the azo initiator AIBN.

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