We reported the preparation of bright and multicolor luminescent colloidal Si nanocrystal (Si-nc) by pulsed UV laser irradiation to porous Si (PSi) in an organic solvent. The different-luminescence-color (different-sized) colloidal Si-nc was produced by the pulsed laser-induced fragmentation of different-sized porous nanostructures. The colloidal Si-nc samples were found to have higher photoluminescence quantum efficiencies (20%–23%) than the PSi samples (1%–3%). The brighter emission of the colloidal Si-nc was attributed to an enhanced radiative band-to-band transition rate due to the presence of a surface organic layer formed by UV laser-induced hydrosilylation.

Ytterbium-based heavy-fermion metals have recently attracted attention as magnetic refrigeration materials generating low-temperature environments below 1 K without using expensive 3He. YbCu4Ni is known to exhibit a giant value of specific heat divided by temperature C/T∼7.5J/K2mol below 0.2 K, implying high potential of magnetic refrigeration. In this paper, we report magnetic refrigeration down to 0.2 K from the initial temperatures of 1.8 K by YbCu4Ni ingots installed in a commercial 4He refrigerator. The performance is consistent with that evaluated by our DC magnetization and specific heat measurements. Our study demonstrates the high performance of YbCu4Ni without precious metals as a magnetic refrigeration material with moderately high density of Yb atoms (∼0.02Ybmol/cm3) and high thermal conductivity.