International audienceSpectroscopic properties of Er3+ ions have been studied in the 60Sb2O3-20WO3-19Na2O-1Bi2O3 (SWNB) glasses doped with 0.25 and 0.50 mol% Er2O3 respectively. The Judd-Ofelt parameters measured from the absorption spectra have been used to calculate the radiative life-time (τr) and the stimulated emission cross section. The low phonon energy, a reduced quenching effect and a high quantum efficiency of 90% for the 1.53 μm expected laser emission into pumping at 980 nm are in favor of promising material laser application
International audienceThe unconventional Heavy Metal Oxide Glasses (HMOG) are characterized by a low phonon energy, large infrared range transmission, high refractive index and nonlinear optical properties. Ternary glasses have been synthesized and studied in the Sb2O3– MoO3-ZnCl2 system. Further, the glass formation compositional limits are reported and some glass samples with the formula: (90-x)Sb2O3 -xMoO3–10 ZnCl2 (10 ≤ x ≤ 50, mole%) were elaborated. Thermal properties have been measured and indicating that the glass transition temperature decreases with increasing proportions of molybdenum oxide. The evolution of density, microhardness and elastic modulus has been studied as functions of parameter x and Raman spectra measurements have been shown the partial conversion of MoO6 octahedral units into MoO4 tetrahedral
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