Thermosonication is an emerging technology useful for inactivating microorganisms and enzymes in fruit juices. However, the effect of the ultrasound processing on the ascorbic acid content is not clear and the results reported in the literature are contradictory. In this work, the impact of sonication and thermosonication on the ascorbic acid content was first evaluated in model systems. Degassed model solutions at four different pH values (3-6) were processed with or without sonication for 60min at two different conditions of temperature (25 and 55°C). In all cases, the ascorbic acid was stable under the treatment. After that, two commercial deaerated fruit juices were processed with and without US at 55°C. The ascorbic acid was also retained in these juices after the ultrasound processing under the most severe conditions studied. In conclusion, previous degassing/deaerating of fruit juices is recommended to prevent ascorbic acid degradation when thermosonication is applied.

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The residues from the harvest of persimmon fruit will be thermally valorised by means of high temperature reactions within a spouted bed reactor. With the aim to obtain valuable information for the design of the device, the thermo-chemical processes were simulated by multi-rate linear non-isothermal Thermogravimetric Analysis (TGA) using O2 as carrier gas. In addition, a set of analyses were carried out using Ar as carrier gas in order to evaluate the influence of the atmosphere (oxidative or inert conditions) on the decomposition of the samples evaluating the reactions of pyrolysis. The release of gases was monitored by Evolved Gas Analysis (EGA) with in-line Fourier Transformed Infrared (FT-IR) analysis. The thermo-chemical reaction was mathematically described through the definition of the main kinetic parameters: activation energy (Ea), pre-exponential factor (ln A) and model and order of reaction (n). The so-called kinetic triplet was calculated through the application of a methodology based on complementary iso-conversional methods. These results will be the initial parameters that will help design the Spouted Bed Reactor and it is envisaged that they will be used in computer simulation software to achieve a better understanding of the process to obtain the optimum operational parameters