We have obtained ceramic composites containing graphene structure, where homogenization process of powdery composite was improved. At first, α-alumina was obtained from local row, which is cheap and available. The obtaining method was developed by our group. Graphene oxide was synthesized from natural graphite. Homogenization was carried out in nanomill with organic binder, which provides for equal distribution and separation of graphene oxide layers (Organic binder behaves as “scotch tape”) during grinding. Some characteristics of ceramic materials have been improved.