N-Alkylation
N-Alkylation O 0268Copper-Promoted C-N and C-O Bond Cross-Coupling with Phenyl and Pyridylboronates. -Acyclic and cyclic esters, as well as anhydride of phenyl boronic acid are efficiently phenylating agents in the title reaction. Furthermore, the first C-N cross-coupling of a heterocyclic boronate (VIII) with heteroarenes, such as (IV) and (VII) is demonstrated. -(CHAN*, D. M. T.; MONACO, K. L.; LI, R.; BONNE, D.; CLARK, C. G.; LAM*, P. Y. S.; Tetrahedron Lett. 44 (2003) 19, 3863-3865; DuPont Crop Prot., Stine-Haskell Res. Cent., Newark, DE 19714, USA; Eng.) -M. Paetzel 33-053
Acetate. -A variety of NH-containing compounds such as amines, amides, imides, ureas, sulfonamides, and carbamates, or of phenols are efficiently arylated with arylboronic acids in the presence of cupric acetate and a tertiary amine as promoter. -(CHAN, D. M. T.; MONACO, K. L.; WANG, R.-P.; WINTERS, M. P.; Tetrahedron
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