Nanowires (NWs), due to their unique highly anisotropic characteristics, hold a great promise to be used in wide technological fields, such as building blocks for data storage and memory, advanced scanning probes, and biotechnological applications. In addition, given the high sensitivity to their environment, NWs can be used as sensor for a number of applications. The fabrication and electrical characterization of NW-based devices can be achieved after proper placing of NWs between electrodes, which represents one of the major challenges in this field. The dielectrophoresis (DEP) method can be used to trap electrically neutral NWs by the application of an alternating electric field between a pair of electrodes. Here, we present a systematic study of DEP parameters as well as electrodes geometry for NW deposition. This method presents a suitable protocol for deposition in a useful and coherent fashion of post-growth electrodeposited NWs and further electrical characterization. This can be used for investigation of the fundamental transport properties of individual NWs and fabrication of NW-based devices, such as sensors and field-effect transistors.