The Nangbéto hydroelectric dam lake, which is a spillway for agricultural input residues, urban and industrial effluents present in the Mono basin, is exposed to all forms of pollution. The aim of this work is to estimate the content of seven trace elements present in the sediments of the aforementioned lake in order to assess the ecological risk incurred by the aquatic biocenosis and therefore by man. Forty-two sediment samples (21 per season) are realized in different areas of the Lake. Cd, Pb, Ni, Cu, Cr, As and Hg are measured out in the sediments by the flame atomic absorption spectrophotometer in these pre-mineralized samples. The results show average contents varying from the lowest level 0.04 mg / kg for Hg to the highest 12.15 mg / kg for Cu in the rainy season and from 0.03 mg / kg for Hg and for As to 9.14 mg/kg for Cu in the dry season. All of these values are below Canadian sediment quality standards. The strongest average geoaccumulation indices (Igeo) are obtained for Pb with values less than 2. The mean values of the contamination factor (FC) are less than 1. The mean indices of contamination (Im) are less than 2, threshold d 'an onset of polymetallic contamination. The ecological risk (Ri) in relation to the contamination of the sediments of the Lake with trace elements is low in any season (Ri <40) and this implies a low risk of contamination of the biocenosis. However, the present study only deals with metallic trace elements. It does not take into account other pollutants, nor the potential "cocktail" effects between them. Additional work should therefore be continued in this direction to consolidate the low risk recorded for the biocenosis. Le Lac du barrage hydroélectrique de Nangbéto qui constitue un déversoir des résidus des intrants agricoles, des effluents urbains et industriels présent dans le bassin du Mono est exposé à toutes formes de pollution. Le but de ce travail est de quantifier les teneurs de sept (7) éléments traces dans les sédiments dudit Lac afin d’évaluer le risque écologique encouru par la biocénose aquatique et partant par l’homme.Quarante-deux (42) échantillons de sédiments (21 par saison) sont échantillonnés dans différentes zones du Lac. Le Cd, Pb, Ni, Cu, Cr, As et Hg sont dosés dans les sédiments par le spectrophotomètre d’absorption atomique à flamme dans ces échantillons minéralisés. Les résultats montrent des teneurs moyennes variant de la plus faible teneur 0,04mg/kg pour le Hg à la plus forte (12,15mg/kg) pour le Cu en saison pluvieuse et de 0,03 mg/kg pour le Hg et pour l’As à la plus forte (9,14 mg/kg) pour le Cu en saison sèche. Toutes ces valeurs sont inférieures aux normes canadiennes de qualité des sédiments. Les plus forts indices de géoaccumulation (Igeo) moyens sont obtenus chez le Pb avec des valeurs inférieures à 2. Les valeurs moyennes de facteur de contamination (FC) sont inférieures à 1. Les indices moyens de contamination (Im) sont inférieurs à 2, seuil d’un début de contamination polymétallique. Le risque écologique (Ri) par rapport à la contamination des sédiments du Lac en éléments traces est faible en toute saison (Ri < 40) et cela implique un faible risque de contamination de la biocénose. La présente étude ne porte toutefois que sur les éléments traces métalliques. Elle ne tient compte ni des autres polluants, ni des effets "cocktail" potentiels entre eux. Un travail complémentaire devra donc être poursuivi dans ce sens pour consolider le faible risque enregistré pour la biocénose.
The Lake Togo-Lagoon of Aného is located in the coastal zone where phosphorite mining is carried out. This mining discharges all kinds of waste such as fuel oil into the surrounding environment without prior treatment. Moreover, the hydrosystem receives runoff and river inputs after having crossed and leached from mining and urban soils. This study aims to determine the polycyclic aromatic hydrocarbons (PAHs) contamination in commercially consumed fish species (Chrysichthys nigrodigitatus) from that hydrosystem and the associated health risks for consumers. For that, fish sample collection was performed during the dry season. Afterwards, their muscles, gills, and livers were cut and 12 PAHs were analyzed using gas chromatography coupled with a mass spectrometer (GC-MS). The total PAHs (tPAHs) concentrations in fish tissues ranged from 5.24 to 48.40 µg/kg with average concentration of 14.51 ± 8.95 µg/kg in muscles, from 5.90 to 28.20 µg/kg averaging 14.90 ± 5.19 µg/kg in gills, and from 43.20 to 149.00 µg/kg with an average of 80.74 ± 27.08 µg/kg in livers. The average concentrations of low molecular weight PAHs (LMW PAHs) were 10.82 ± 9.61 µg/kg in muscles, 8.25 ± 5.43 µg/kg in gills, and 47.97 ± 22.56 µg/kg in livers whereas those of high molecular weight of PAHs (HMW PAHs) were 4.10 ± 2.14 µg/kg in muscles, 7.98 ± 3.96 µg/kg in gills, and 32.77 ± 8.66 µg/kg in livers. An overall trend of decreasing concentrations with increasing fish size classes was observed for some PAHs (Naphtalene, Pyrene in muscles, for Pyrene, Benzo(a)Anthracene, Chrysene in gills and for Naphtalene, Phenanthrene in livers). The PAHs in these fish might have pyrogenic and petrogenic sources, with the dominance of pyrogenic, and all of the total hazard quotients (THQ) are less than 1. This situation must not be neglected for better planning sustainable management of the target ecosystem.
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