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No abstract

The synthesis and crystal structure of ((C2H5)4N) {Ni (C3S5)2} is described. Space group P21/n with a=7. 333(1)Å, b=25.734(3)Å, c=12.798(4)Å, β=104.95(2)° and Z=4. The structure consists of a one‐dimensional zig‐zag chain with alternating Ni‐Ni distances of 4.163Å and 4.243Å, respectively. The temperature dependence of the conductivity shows an unusual behaviour. The relationship ln(σ) ∞ T1/2 is followed instead of the common semiconductor behaviour of ln(σ) ∞ l/T. The unexpectedly high value of the conductivity is related to the size of the counter cation in the crystal lattice.

. (1987). Crystal structure and conductivity of the organometallic linear chain system (Et4N)[Ni(dmit)2] and related compounds. Synthetic Metals,, 745-750. DOI: 10.1016/0379-6779(87)90446-2 General rightsCopyright and moral rights for the publications made accessible in the public portal are retained by the authors and/or other copyright owners and it is a condition of accessing publications that users recognise and abide by the legal requirements associated with these rights.• Users may download and print one copy of any publication from the public portal for the purpose of private study or research.• You may not further distribute the material or use it for any profit-making activity or commercial gain • You may freely distribute the URL identifying the publication in the public portal ? Take down policyIf you believe that this document breaches copyright please contact us providing details, and we will remove access to the work immediately and investigate your claim.

DOI to the publisher's website. • The final author version and the galley proof are versions of the publication after peer review. • The final published version features the final layout of the paper including the volume, issue and page numbers. Link to publication General rights Copyright and moral rights for the publications made accessible in the public portal are retained by the authors and/or other copyright owners and it is a condition of accessing publications that users recognise and abide by the legal requirements associated with these rights. • Users may download and print one copy of any publication from the public portal for the purpose of private study or research. • You may not further distribute the material or use it for any profit-making activity or commercial gain • You may freely distribute the URL identifying the publication in the public portal. If the publication is distributed under the terms of Article 25fa of the Dutch Copyright Act, indicated by the "Taverne" license above, please follow below link for the End User Agreement: