The optogeometric properties of various sensitive thin films involved in gas sensing applications are investigated by using the m-line technique and atomic force microscopy. Variations of these optical properties are studied under butane and ozone exposure.
We report the detection of 100 ppm of butane in superatmospheric N 2 or air with an m-lines setup. The sensing elements are ZnO-nanostructured coatings prepared by pulsed laser deposition. The deposition technique was optimized to obtain highly transparent films of 1 cm 2 in area and several hundreds nanometer thick. ZnO structures preserve gas sensitivity even when deposited at room temperature. Refractive index variations down to 0.005 were detected and typical variations of about 20% were induced during ZnO film-butane contact.
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