The isolation and identification of twenty‐two components (including one new compound) from the whole herb of Clinoponium laxiflorum (Hay) Matsum (Labiatae) are described. Their structures were determined on the basis of spectral and chemical transformation. One new compound is methyl rosmarinate. The other twenty‐one compounds include three steroids (α‐spinasterol, α‐spinasteryl‐3‐O‐β‐D‐glucopyranoside, and β‐sitosteryl‐3‐O‐β‐glucopyranoside), three triterpenes (oleanolic acid, ursolic acid, and betulinic acid), nine flavonoids (didymin, apigenin‐7‐O‐β‐glucopyranoside, luteolin‐7‐O‐β‐glucopyranoside, isosakuranetin, narigenin, apigenin, luteolin, narirutin, and hesperidin), three lignolic acids (rosmarinic acid, 3‐(3,4‐dihydroxyphenyl)lactic acid, and caffeic acid), and three phenols (4‐hydroxybenzaldehyde, 3,4‐dihydroxybenzaldehyde, and 3,4‐dihydroxybenzoic acid).
The isolation and identification of fifteen crystalline components from the whole herb of Clinopodium umbrosum (Bieb.) C. Koch (Labiatae) are described. Their structures were determined on the basis of spectral evidence and chemical transformation. These compounds include five steroids (a-spinasterone, {1-sitosterol, stigmasterol, a-spinasterol, and a-spinasteryl-3-0-P-glllcopyranoside), four triterpenoids (3J5-hydroxyurs-11-en-28,13-olide, betulinic acid, oleanolic acid, ursolic acid), four flavonoids (luteolin, luteolin-7-0-{1-g1ucopyranoside, apigcnin-7-0-{1-glucuronide, and apigenin-7-0-tB-methylglucuronate), and two lignolic acids [3-(3,4-dihydroxyphenyl)-lactic acid and rosmarinic acid].
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