In this paper the features of separation processes modelling are analyzed in hydrocarbonic media within the limits of thermodynamics of equilibrium states. Approaches to calculation of phase equilibrium in multicomponent systems are discussed. Regularities and peculiarities of composition change of gas mixture depending on the temperature and pressure are studied. It has been established that there are specific conditions of non-monotonic change of composition with extremums for some separation regimes that significantly influences the physical properties and intensity of exchange processes at the heat-and mass transfer in multicomponent hydrocarbon media. In addition, the details of the behavior of gas phase with changing its thermal and physical properties have been discussed. Also, the calculated distributions of Prandtl, Schmidt and Lewis-Semenov numbers essentially influencing on the intensity of transport processes are considered.
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